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When Damon was about to stab Caroline, Stefan stopped him, promising her that he would never let anything happen to her.

A few days later, Stefan and Caroline still cannot make physical contact and try to convince two of the heretics, Mary Louise and Nora, to siphon the spell off of Caroline.

They decide to attend The "Heaven and Hell" ball where they force Nora to siphon the spell off of Caroline after threatening Mary Louise's life.

After her mother was diagnosed with cancer, Stefan stuck by Caroline through her grief and they made up.

Caroline gets released by Lily but still had "vervain skin".

Upon learning of Bonnie's death, Stefan told Caroline that he would always be there for her as she has always been there for him.

In Season Six, Caroline and Stefan haven't seen and spoken in four months after the death of Bonnie and Damon.

In one conversation, he told her that she reminded him to his best friend Lexi who was killed by Damon.